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MATERIAL SAFETY DATA SHEET Personal Protective Equipment See Section 8. 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product code: Product Name: Chemical Name:
3-Quinolinecarboxylic acid, 1-cyclopropyl-6-fluoro-1,4-dihydro-4-oxo-7-(1-piperazinyl)-, monohydrochloride hydrate
Synonyms:
3-Quinolinecarboxylic acid, 1-cyclopropyl-6-fluoro-1,4-dihydro-4-oxo-7-(1-piperazinyl)-, monohydrochloride, monohydrateCiprofloxacin hydrochloride monohydrateCiprofloxacin hydrochloride hydrate
Recommended use: Formula: Supplier:
Spectrum Chemicals and Laboratory Products, Inc. 14422 South San Pedro St. Gardena, CA 90248(310) 516-8000
Emergency Telephone Number: Contact Person: Contact Person: 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
May cause skin and eye irritation. May cause irritation of respiratory tract. Physical state: Appearance: OSHA Regulatory Status
This material is not considered hazardous by the OSHA Hazard CommunicationStandard (29 1910.1200)
Product code: C2213 Product name: CIPROFLOXACIN 2. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS Principal Routes of Exposure: Ingestion. Inhalation. Acute Potential Health Effects: Skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: May cause irritation of respiratory tract. Ingestion: Ingestion may cause vomiting and nausea. May cause abdominal discomfort. May cause diarrhea. May cause constipation. It may affect the kidneys. May affect the liver. May cause central nervous system effects. May affect the blood. May affect the cardiovascular system. Chronic Potential Health Effects: Target Organs:
Kidneys. Liver. Central nervous system. Musculoskeletal system (joints, tendons). Carcinogen Status: Mutagenic Effects:
May affect genetic materialExperiments with bacteria have shown mutagenic effectsAnimal experiments showed mutagenic effectsExperiments with human lymphocytes have shown mutagenic effects
Teratogenic Effects: Aggravated Medical Conditions: Liver disease. Kidney disease. Heart condition. Seizures. Hypersensitivity to
material. Hypersensitivity to fluoroquinolones. Flare-up of gout. Worsening ofmyasthenia gravis. See Section 11 for additional Toxicological Information POTENTIAL ENVIRONMENTAL EFFECTS 3. COMPOSITION/INFORMATION ON INGREDIENTS Components 4. FIRST AID MEASURES General Advice:
Poison information centres in each State capital city can provide additionalassistance for scheduled poisons (13 1126)
Product code: C2213 Product name: CIPROFLOXACIN Skin Contact:
Wash off immediately with soap and plenty of water removing all contaminatedclothes and shoes. Get medical attention if irritation develops. Eye Contact:
Flush eye with water for 15 minutes. Get medical attention if irritation occurs. Ifsymptoms persist, call a physician. Inhalation:
Move to fresh air. If breathing is difficult, give oxygen. In case of shortness of breath,give oxygen. Get medical attention. Ingestion:
Do not induce vomiting without medical advice. Never give anything by mouth to anunconscious person. Consult a physician if necessary. Notes to Physician: 5. FIRE-FIGHTING MEASURES Flammable Properties Flashpoint (°C/°F): Tested according to: Not applicable Lower Explosion Limit (%): Upper Explosion Limit (%): Autoignition Temperature (°C/°F): No information available Suitable Extinguishing Media:
Carbon dioxide (CO2). Dry chemical. Water spray mist orfoam. Unsuitable Extinguishing Media: Hazardous Combustion Products: Specific hazards:
May be combustible at high temperatures. Special Protective Equipment for Firefighters:
As in any fire, wear self-contained breathing apparatuspressure-demand, MSHA/NIOSH (approved or equivalent)and full protective gear
Specific Methods: 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Ensure adequate ventilation. Use personal protective equipment. Avoid contact with skin, eyes and clothing. Avoid dust formation. Remove all sources of ignition. Environmental Precautions: No information available. Methods for Cleaning Up: Sweep up and shovel into suitable containers for disposal. Avoid dust formation. Clean contaminated surface thoroughly. Product code: C2213 Product name: CIPROFLOXACIN 7. HANDLING AND STORAGE Handling Technical Measures/Precautions: Provide sufficient air exchange and/or exhaust in work rooms. Avoid dust formation. All equipment used when handling the product must be grounded. Keep away from incompatible materials. Safe Handling Advice: Wear personal protective equipment. Avoid contact with skin, eyes and clothing. Avoid dust formation. Do not ingest. Do not breathe vapours/dust. Keep away from heat and sources of ignition. Handle in accordance with good industrial hygiene and safety practice. Technical Measures/Storage Conditions: Keep container tightly closed in a dry and well-ventilated place. Store at room temperature in the original container. Sensitive to light. Store in light-resistant containers. Store away from incompatible materials. Incompatible Products: Oxidizing agents. Iron. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure:
Ensure adequate ventilation. Use process enclosures, localexhaust ventilation, or other engineering controls to keepairborne levels below recommended exposure limits. If useroperations generate dust, fume or mist, use ventilation tokeep exposure to airborne contaminants below the exposurelimit. Personal Protective Equipment Eye protection:
Safety glasses. Safety glasses with side-shields. Skin and body protection:
Long sleeved clothing. Chemical resistant apron. Gloves. Respiratory protection: Hygiene measures:
Avoid contact with skin, eyes and clothing. Wash hands before breaks andimmediately after handling the product. When using, do not eat, drink or smoke. National occupational exposure limits United States U.S Occupational Exposure Limits: Not determined Canada Canada Occupational Exposure Limits: Not determined Australia and Mexico Occupational Exposure Limits for Australia and Mexico: Not determined 9. PHYSICAL AND CHEMICAL PROPERTIES Product code: C2213 Product name: CIPROFLOXACIN 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Appearance: Molecular/Formula weight: Flash point (°C): Lower Explosion Limit (%): Upper Explosion Limit (%): Autoignition Temperature (°C/°F): Boiling point/range(°C/°F): Melting point/range(°C/°F): Decomposition temperature(°C/°F): Specific gravity: Density (g/cm3): Bulk density: Vapor pressure @ 20°C (kPa): Vapor density: Evaporation rate: VOC content (g/L): Odor threshold (ppm): Partition coefficient Miscibility: (n-octanol/water): Solubility: Sparingly soluble in water Very slightly soluble in Ethanol Slightly soluble in glacial Acetic acid Slightly soluble in Methanol Practically insoluble in Acetone Practically insoluble in Acetonitrile Practically insoluble in Dichloromethane Practically insoluble in Ethyl Acetate Practically insoluble in Hexane 10. STABILITY AND REACTIVITY Stability: Conditions to avoid:
Heat. Avoid dust formation. Dust may form explosive mixture in air. Fine dustdispersed in air in sufficient concentrations, and in the presence of an ignition sourceis a potential dust explosion hazard. Incompatible materials. Materials to avoid: Hazardous decomposition products: Possibility of Hazardous Reactions: Polymerization: Corrosivity: Special Remarks on Corrosivity: No information available Product code: C2213 Product name: CIPROFLOXACIN 11. TOXICOLOGICAL INFORMATION Acute Toxicity Component Information Ciprofloxacin Hydrochloride - 86393-32-0LD50/oral/rat = No information available LD50/oral/mouse = No information available LD50/dermal/rabbit = No information available LD50/dermal/rat = No information available LC50/inhalation/rat = No information available LC50/inhalation/mouse = No infomaton available Other LD50 information = No information available Product Information LC50/inhalation/rat = No information available LC50/Inhalation/mouse = No information available LD50/dermal/rabbit = No information available LD50/dermal/rat = No information available LD50/oral/rat = No information available LD50/oral/mouse = No information available Local Effects Skin irritation: Eye irritation:
Contact with eyes may cause irritation. May cause burning, itching, tearing,conjunctival hyperemia, lid edema, keratitis, decreased vision, photophobia. Inhalation:
May cause irritation of respiratory tract. Ingestion:
Ingestion may cause nausea, vomiting, diarrhea. May cause constipation. May causeupset stomach. May cause abdominal pain. May cause heartburn. May causedyspepsia. May cause dysphagia (difficulty swallowing; pain while swallowing). Maycause flatulence. May cause dry mouth. May cause pain in the mouth with redness,blistering, white patches or sores. May affect behavior/central nervous system(somnolence, tremor, hallucinations). May affect the cardiovascular system (pulserate, hypotension, hypertension, palpitations, atrial flutter, angina pectoris, syncope,vasculitis). May affect the blood (changes in white blood cell count, hemolyticanemia, methemoglobinemia). It may affect the spleen. It may affect the pancreas(pancreatitis). May cause hyperglycemia. May cause hyperkalemia. Sensitization: Chronic Toxicity Product code: C2213 Product name: CIPROFLOXACIN Chronic Toxicity
Prolonged or repeated ingestion may affect behavior/central nervous system(headache, somnolence, weakness, lethargy, fatigue, drowsiness, hallucinations,agitation, restlessness, irritability, confusion, tremor, delirium, nightmares, insomnialightheadness, ataxia, seizures, dizziness, ). Prolonged or repeated ingestion mayaffect the musculoskeletal system (joints, tendons) and cause tendonitis, tendonrupture, myalgia, myoclonus, joint pain or stiffness, back or neck pain. Prolonged orrepeated ingestion may affect the liver (jaundice, liver function tests impaired, hepaticnecrosis), and urinary system/kidneys (nephritis, hematuria, cylindruria, renal failure,urinary retention, polyuria, urethral bleeding, renal calculi, interstitial nephritis). Prolonged or repeated ingestion may affect the blood (changes in cell count,eosinophilia, agranulocytosis, leukopenia, leukocytosis, pancytopenia). Prolonged orrepeated ingestion may cause cutaneous candidiasis, photosensitivity,hyperpigmentation, and hypersensitivity or anaphylactic reactions such dermatitis,urticaria, flushing, rash, erythema nodosum, swellling of the lips, neck, face,conjunctivae, hands, angioedema, difficulty breathing, shortness of breath, Stevens-Johnson syndrome. Carcinogenic effects: Mutagenic Effects:
May affect genetic materialExperiments with bacteria have shown mutagenic effectsAnimal experiments showed mutagenic effectsExperiments with human lymphocytes have shown mutagenic effects
Reproductive Effects: Teratogenic Effects: Target Organs:
Kidneys. Liver. Central nervous system. Musculoskeletal system (joints, tendons). 12. ECOLOGICAL INFORMATION ECOTOXICITY Toxicity to terrestrial and aquatic plants and animals: Ecotoxicity effects: Aquatic toxicity: Mobility: Persistence and degradability: Bioaccumulative potential: 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: Waste must be disposed of in accordance with Federal, State and Local regulation. Contaminated packaging: Empty containers should be taken for local recycling, recovery or waste disposal Components RCRA - F Series Wastes RCRA - K Series Wastes RCRA - P Series Wastes RCRA - U Series Wastes Product code: C2213 Product name: CIPROFLOXACIN 14. TRANSPORT INFORMATION Proper Shipping Name: Hazard Class: Packing Group: Subsidiary Risk: Marine Pollutant DOT RQ (lbs): TDG (Canada) Proper Shipping Name: Hazard Class: Packing Group: Subsidiary Risk: Description: Proper Shipping Name: Hazard Class: Packing Group: Subsidiary Risk: Classification Code: Description: CEFIC Tremcard No: IMO / IMDG Proper Shipping Name: Hazard Class: Subsidiary Risk: Packing Group: Description: IMDG Page: Marine Pollutant Maximum Quantity: Proper Shipping Name: Hazard Class: Packing Group: Subsidiary Risk: Classification Code: Description: Hazard Class: Proper Shipping Name: Packing Group: Subsidiary Risk: Product code: C2213 Product name: CIPROFLOXACIN Description: Proper Shipping Name: Hazard Class: Packing Group: Subsidiary Risk: Description: 15. REGULATORY INFORMATION International Inventories Components U.S. TSCA Philippines Australia EINECS-No. U.S. Regulations California Prop. 65: Safe Drinking Water and Toxic Enforcment Act of 1986. Chemicals Known to the State of California to Cause Cancer: This product does not contain a chemical requiring a warning under California Prop. 65. (See table below) Chemicals Known to the State of California to Cause Reproductive Toxicity: This product does not contain a chemical requiring a warning under California Prop. 65. (See table below) Components Carcinogen Developmental Toxicity Male Reproductive Female Reproductive Toxicity Toxicity: CERCLA/SARA Components CERCLA - Hazardous Section 302 Extremely Section 302 Extremely Section 313 - Section 313 - Reporting Substances and their Hazardous Hazardous Chemical Category de minimis Reportable Quantities Substances and TPQs Substances and RQs U.S. TSCA Components TSCA Section 5(a)2 - Chemicals With Significant TSCA 8(d) -Health and Safety Reporting New Use Rules (SNURS) WHMIS hazard class: Non-controlled Canada Controlled Products Regulation: This product has been classified according to the hazard criteria of the CPR (Controlled Products Regulation) and the MSDS contains all of the information required by the CPR. Inventory Product code: C2213 Product name: CIPROFLOXACIN Components Canada (DSL) Canada (NDSL) EU Classification R -phrase(s) not determined S -phrase(s) none The product is classified in accordance with Annex VI to Directive 67/548/EEC Indication of danger: Not dangerous 16. OTHER INFORMATION The MSDS format complies with ANSI Z400.1-2004 standards. Preparation Date Reason for revision: Prepared by: Literature reference:
All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS)applies only to the material as packaged. If this product is combined with other materials, deteriorates, or becomescontaminated, it may pose hazards not mentioned in this MSDS. The physical properties reported in this MSDS areobtained from the literature and do not constitute product specifications. Information contained herein does not constitutea warranty, whether expressed or implied, as to the safety, merchantability or fitness of the goods for a particular purpose. Spectrum Chemicals & Laboratory Products, Inc. assumes no responsibility for results obtained or for incidental orconsequential damages, including lost profits, arising from the use of these data. No warranty against infringement of anypatent, copyright or trademark is made or implied. It shall be the user's responsibility to develop proper methods ofhandling and personal protection based on the actual conditions of use. While this MSDS is based on technical datajudged to be reliable, Spectrum assumes no responsibility for the completeness or accuracy of the information containedherein. Product code: C2213 Product name: CIPROFLOXACIN
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