Microsoft word - m0111.doc

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Section 1 – Company Name and Product Information
Company Name: Alliance Group, Inc.
Address: N114 W18621 Clinton Drive
Product name: Oxytrol
Product code: 0111
Chemical Family: Sulfite Solution
Revised MSDS:
Section 2 – Hazards Identification
EMERGENCY OVERVIEW: DANGER! CORROSIVE. Harmful or fatal if swallowed. Harmful if inhaled.
May cause an allergic reaction to skin, respiratory tract or if swallowed.
Physical State:
Routes Of Exposure: Eyes. Ingestion. Inhalation. Skin.
Target Organs: None known.
Eye Contact: Solutions will cause irritation or burns to the eyes.
Skin Contact: Contact may cause: allergic skin reaction. Solutions will cause skin irritation. Skin
No data available.
Inhalation: Dusts or mists may irritate: respiratory tract. May cause severe or deadly allergic reaction in
some asthmatics or sulfite sensitive individuals. Possible signs and symptoms of allergic reaction may
include hives, respiratory distress, flushing, gastrointestinal disturbances and contact dermatitis. Severe
cases result in respiratory arrest, unconsciousness or coma.
Ingestion: May cause: gastrointestinal irritation. nausea. vomiting. death. Large amounts may cause:
violent colic. diarrhea. circulatory disturbances. central nervous system depression. May cause severe or
deadly allergic reaction in some asthmatics or sulfite sensitive individuals.
Medical Conditions Aggravated By Exposure To Product: Respiratory system disorders. May cause
severe and possibly fatal allergic reactions if inhaled or swallowed by some asthmatics and sulfite-
sensitive individuals.
Other: This product is not for drug use. Only Food Grade material is for use as a food additive.
Cancer Information: This product does not contain greater than 0.1% of the known or potential carcinogens
listed in NTP, IARC, or OSHA.
Potential Environmental Effects: See Section 12.
Section 3 – Composition / Hazardous Ingredients
CAS Number
Chemical Component
% by Weight
OSHA Hazard
Section 4 – First Aid Measures
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes while holding eyelids
open. Tilt head to avoid contaminating unaffected eye. Get immediate medical attention.
Skin Contact: Immediately flush skin with plenty of water while removing contaminated clothing and
shoes. Do not reuse clothing or shoes until cleaned. If irritation develops or persists, get medical attention.
Wash with soap and water.
Inhalation: Remove to fresh air. If breathing is difficult, administer oxygen. If not breathing, give
artificial respiration, preferably mouth-to-mouth. GET MEDICAL ATTENTION IMMEDIATELY.
Ingestion: If swallowed, wash out mouth with water provided person is conscious. Call a physician
immediately. Give 1-2 glasses of water to drink.
Note to Physicians: Treat symptomatically. Note potential for anaphylactic shock with allergic individuals.
Risk of sulfur dioxide formation by reaction with gastric acid after swallowing.
Section 5 - Fire Fighting Measures
Flash Point: None.
Lower Explosion Limit: N.A.
Upper Explosion Limit: N.A.
Extinguishing Media: Not flammable. Use extinguishing agents appropriate for surrounding fire.
Fire Fighting Methods: Evacuate area of unprotected personnel. Wear protective clothing including
NIOSHApproved self-contained breathing apparatus. Remain upwind of fire to avoid hazardous vapors
and decomposition products. Use water spray to cool fire exposed containers and disperse vapors.
Fire And Explosion Hazards: None known.
Hazardous Combustion Products: At elevated temperatures, product will decompose generating: Sulfur
Section 6 – Accidental Release Measures
Spill Clean-Up Procedures: CORROSIVE MATERIAL. Evacuate unprotected personnel from area.
Maintain adequate ventilation. Follow personal protective equipment recommendations found in Section 8.
Never exceed any occupational exposure limit. Contain spill, place into drums for proper disposal. Flush
remaining area with water to remove trace residue and dispose of properly. Provide ventilation to clear
sulfur dioxide fumes which may be generated by the sodium sulfite component. Avoid direct discharge to
sewers and surface waters. Notify authorities if entry occurs.
Section 7 - Handling and Storage
Handling: Avoid contact with eyes, skin, and clothing. Use with adequate ventilation. Do not swallow.
Avoid breathing vapors, mists, or dust. Do not eat, drink, or smoke in work area. Wash thoroughly after
Storage: CORROSIVE MATERIAL. Store in a cool, well ventilated area, out of direct sunlight. Store in a
dry location away from heat. Keep away from incompatible materials. Keep containers tightly closed. Do
not store in unlabeled or mislabeled containers. Keep containers tightly closed. Do not store in unlabeled
or mislabeled containers
Section 8 – Exposure Control / Personal Protection
Exposure Guidelines:

Engineering Controls: General room ventilation and local exhaust are required. Avoid creating dust or
mist. Maintain adequate ventilation. Do not use in closed or confined spaces. Keep levels below exposure
limits. To determine exposure levels, monitoring should be performed regularly.
Eye/Face Protection: Wear chemical safety goggles while handling this product. Do not wear contact
Skin Protection: Prevent contact with this product. Wear gloves and protective clothing depending on
condition of use. Protective gloves: Impervious.
Respiratory Protection: Respiratory protection may be required to avoid overexposure when handling
this product. If exposure limits are exceeded, wear: NIOSH-Approved respirator for dusts, mists, and/or
SO2 vapors as conditions indicate. NIOSH-Approved Supplied Air Respirator (SAR). NIOSH-Approved
self-contained breathing apparatus. DO NOT exceed limits established by the respirator manufacturer. All
respiratory protection programs must comply with OSHA 29 CFR 191 0.134 and ANSI Z88.2 requirements
and must be followed whenever workplace conditions require a respirator's use.
Other Protective Equipment: Eye-wash station. Safety shower. Rubber apron. Rubber boots. Protective
General Hygiene Conditions: Wash with soap and water before meal times and at the end of each work
Section 9 – Physical and Chemical Properties.
Physical State:
Color: Clear. Water white
Specific Gravity:
Solubility in water:
Freezing Point:
% Volatiles: N.D.
Vapor Pressure:
Vapor Density: N.D.
Section 10 – Stability and Reactivity
Stability: Stable under normal conditions.
Conditions To Avoid: Avoid elevated temperatures.
Incompatible Materials: Acids. Oxidizing agents. Nitrites. Nitrates.
Hazardous Decomposition Products: Sulfur dioxide. Sulfur oxides. Sodium sulfide residue.
Possibility of Hazardous Reactions: Hazardous polymerization will not occur under normal conditions.
Contact with acids will release sulfur dioxide. Contact with strong oxidizers causes vigorous exothermic
Section 11 – Toxicological Information
LD50 Oral:
LD50 Skin:
LC50 Inhalation:
Section 12 – Ecological Information
Ecotoxicological Information:
Chemical Fate Information:
Section 13 –Disposal Considerations
Hazardous Waste Number: N.A.
Waste disposal methods: Dispose of in accordance with all local, state, and federal regulations.
Regulations may vary in different locations. Since emptied containers retain product residue, follow label
warnings even after container is emptied.
Section 14 – Transportation Information
Proper Shipping Name: Corrosive liquid, basic, inorganic, n.o.s. (contains sodium sulfite)
Hazard Class: 8
UN Number: UN3266
Packing Group: II
Label required: Corrosive
Section 15 – Regulatory Information
TSCA Inventory Status: This product or all components of this product are listed on the Inventory of Chemical
SARA Title III Section 311/312 Category:
Immediate (Acute) Health Hazard:
SARA Section 302/304/313/HAP:

California - The following components are listed under Proposition 65: Lead <= 3 ppm
Wisconsin :The following components are listed as a Wisconsin HAP: None
Section 16 –Additional Information
HMIS/NFPA Label Information
Complies with CFR Title 21 Section 173.310 for boiler water and steam which may contact dairy
MSDS DATED: December 1, 2008
MSDS Prepared by:
Reason for Revision: Change in format.
The data in this Material Safety Data Sheet relates to the specific material designated and does not relate to its use in
combination with any other material or process. The data contained is believed to be correct. However, since
conditions of use are outside our control it should not be taken as warranty or representation for which Alliance
Group, Inc. assumes legal responsibility. This information is provided solely for your consideration, investigation,
and verification.


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