Document

1. Identification of the substance/mixture and of the company/undertaking Tetramethrin - Permethrin - Piperoniyl butoxide 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet e-mail address of the competent personresponsible for the Safety Data Sheet CNIT - Centro Nazionale Informazione Tossicologia: (39) 0382-525005 2.1. Classification of the substance or mixture.
The product is classified as hazardous pursuant to the provisions set forth in Directives 67/548/EEC and 1999/45/EC and/or EC Regulation1272/2008 (CLP) (and subsequent amendments and supplements). The product thus requires a safety datasheet that complies with theprovisions of EC Regulationn 1907/2006 and subsequent amendments. Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet.
The full wording of the Risk (R) and hazard (H) phrases is given in section 16 of the sheet.
Hazard labelling pursuant to Directives 67/548/EEC and 1999/45/EC and subsequent amendments and supplements.
VERY TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE AQUATICENVIRONMENT.
VAPOURS MAY CAUSE DROWSINESS AND DIZZINESS.
KEEP AWAY FROM FOOD, DRINK AND ANIMAL FEEDINGSTUFFS.
KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING.
WHEN USING DO NOT EAT, DRINK OR SMOKE.
DO NOT BREATHE GAS/FUMES/VAPOUR/SPRAY (APPROPRIATE WORDING TO BE SPECIFIED BY THEMANUFACTURER).
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND SEEK MEDICALADVICE.
IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE IMMEDIATELY (SHOW THE LABELWHERE POSSIBLE).
AVOID RELEASE TO THE ENVIRONMENT. REFER TO SPECIAL INSTRUCTIONS/SAFETY DATA SHEETS.
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use.
Do not spray on bright flame or any incandescent material.
Keep away from sources of ignition – No smoking.
Keep out of the reach of the children.
3. Composition/information on ingredients.
Carc. 1B H350, Muta. 1B H340, Asp. Tox. 1 H304, Note H P Flam. Liq. 2 H225, Eye Irrit. 2 H319, STOT SE 3 H336 Acute Tox. 3 H331, Aquatic Chronic 1 H410 Acute Tox. 4 H332, Acute Tox. 4 H302, Skin Sens. 1 H317,Aquatic Chronic 1 H410 Eye Irrit. 2 H319, Aquatic Chronic 1 H410 T+ = Very Toxic(T+), T = Toxic(T), Xn = Harmful(Xn), C = Corrosive(C), Xi = Irritant(Xi), O = Oxidizing(O), E = Explosive(E), F+ = Extremely Flammable(F+), F = Highly Flammable(F), N =Dangerous for the Environment(N) The full wording of the Risk (R) and hazard (H) phrases is given in section 16 of the sheet.
4.1. Description of first aid measures.
EYES: Irrigate copiously with clean, fresh water for at least 15 minutes. Seek medical advice.
SKIN: Wash immediately with plenty of water. Remove contaminated clothing. If irritation persists, seek medical attention. Washcontaminated clothing before using them again.
INHALATION: Remove to open air. If breathing is irregular, seek medical advice.
INGESTION: Obtain immediate medical attention. Induce vomiting only if indicated by the doctor. Never give anything by mouth to anunconscious person.
4.2. Most important symptoms and effects, both acute and delayed.
For symptoms and effects caused by the contained substances see chap. 11.
4.3. Indication of any immediate medical attention and special treatment needed.
SUITABLE EXTINGUISHING MEDIA The extinction equipment should contain carbon dioxide, foam or chemical powders. For product leaks and spills that have not caught fire,nebulised water can be used to dispel flammable fumes and protect the individuals taking part in stemming the leak.
EXTINGUISHING MEDIA WHICH SHALL NOT BE USED FOR SAFETY REASONSDo not use jets of water. Water is not effective for putting out fires but can be used to cool containers exposed to flames to preventexplosions.
5.2. Special hazards arising from the substance or mixture.
HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE Excess pressure may form in containers exposed to fire at a risk of explosion.
Do not breathe combustion products (carbon oxide, toxic pyrolysis products, etc).
GENERAL INFORMATION Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous forhealth. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose ofcontaminated water and the remains of the fire according to applicable regulations.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERSHardhat with visor, fireproof clothing (fireproof jacket and trousers with ties around arms, legs and waist) work gloves (fireproof, cut proof anddielectric), self-respirator (self-protector).
6.1. Personal precautions, protective equipment and emergency procedures.
Eliminate sources of ignition (cigarettes, flames, sparks, etc.) from the air in which the leak occurred. If there are no contraindications, spraysolid products with water to prevent the formation of dust. Use breathing equipment if fumes or powders are released into the air. Block theleakage if there is no hazard. Do not handle damaged containers or leaked product before donning appropriate protective gear. Send awayindividuals who are not suitably equipped. For information on risks for the environmental and health, respiratory tract protection, ventilationand personal protection equipment, refer to the other sections of this sheet.
The product must not penetrate the sewers, surface water, ground water and neighbouring areas.
6.3. Methods and material for containment and cleaning up.
For liquid products, suck into a suitable container (made of material not incompatible with the product) and soak up any leaked product withabsorbent inert material (sand, vermiculite, diatomeous earth, Kieselguhr, etc). Collect the majority of the remaining material and deposit incontainers for disposal. For solid products, use spark proof mechanical tools to collect the leaked product and place in plastic containers. Ifthere are no contraindications, use jets of water to eliminate product residues. Make sure the leakage site is well aired. Contaminatedmaterial should be disposed of in compliance with the provisions set forth in point 13.
Any information on personal protection and disposal is given in sections 8 and 13.
Avoid the accumulation of electrostatic charges.
Vapours may ignite with explosion, it is therefore necessary to avoid accumulation keeping the windows and doors open, ensuringcrossventilation. Without adequate ventilation, the vapours may accumulate at the bottom and ignite at a distance, if triggered off, with the riskof flashback. Keep far away from sources of heat, sparks and bright flames. Do not smoke, use matches or lighters. Keep the containersearthed while decanting and wear antistatic boots. Vigorous stirring and flow through the pipings and equipment may cause the formation and accumulation of electrostatic charges due to thelow conductivity of the product. In order to avoid the risk of fire outbreak and explosion never use compressed air during movement.
7.2. Conditions for safe storage, including any incompatibilities.
Store the containers sealed and in a well ventilated place.
8. Exposure controls/personal protection.
As the use of adequate technical equipment must always take priority over personal protection equipment, make sure that the workplace iswell aired through effective local aspiration or bad air vent. If such operations do not make it possible to keep the concentration of the productbelow the permitted workplace exposure thresholds a suitable respiratory tract protection must be used. See product label for hazard detailsduring use. Ask your chemical substance suppliers for advice when choosing personal protection equipment. Personal protection equipmentmust comply with the rules in force indicated below.
HAND PROTECTIONProtect hands with category I (ref. Directive 89/686/EEC and standard EN 374) work gloves, such as those in latex, PVC or equivalent. Thefollowing should be considered when choosing work glove material: degradation, breakage times and permeation. Work glove resistance topreparations should be checked before use, as it can be unpredictable. Gloves’ limit depends on the duration of exposure.
EYE PROTECTIONWear protective airtight goggles (ref. standard EN 166).
SKIN PROTECTIONWear category I professional long-sleeved overalls and safety footwear (ref. Directive 89/686/CEE and standard EN 344). Wash body withsoap and water after removing overalls.
RESPIRATORY PROTECTIONIf the threshold value for one or more of the substances present in the preparation for daily exposure in the workplace or to a fractionestablished by the company’s prevention and protection service is exceeded, wear an FFP3 (ref. standard EN 141) type half mask.
The use of breathing protection equipment, such as masks with organic vapour and dust/mist cartridges, is necessary in the absence oftechnical measures limiting worker exposure. The protection provided by masks is in any case limited.
If the substance in question is odourless or its olfactory threshold is higher than the relative exposure limit and in the event of an emergency,or when exposure levels are unknown or the concentration of oxygen in the workplace is less than 17% volume, wear self-contained,open-circuit compressed air breathing apparatus (ref. standard EN 137) or fresh air hose breathing apparatus for use with full face mask, halfmask or mouthpiece (ref. standard EN 138).
As the use of adequate technical equipment must always take priority over personal protection equipment, make sure that the workplace iswell aired through effective local aspiration or bad air vent. If such operations do not make it possible to keep the concentration of the productbelow the permitted workplace exposure thresholds a suitable respiratory tract protection must be used. See product label for hazard detailsduring use. Ask your chemical substance suppliers for advice when choosing personal protection equipment. Personal protection equipmentmust comply with the rules in force indicated below.
HAND PROTECTIONProtect hands with category I (ref. Directive 89/686/EEC and standard EN 374) work gloves, such as those in latex, PVC or equivalent. Thefollowing should be considered when choosing work glove material: degradation, breakage times and permeation. Work glove resistance topreparations should be checked before use, as it can be unpredictable. Gloves’ limit depends on the duration of exposure.
EYE PROTECTIONWear protective airtight goggles (ref. standard EN 166).
SKIN PROTECTIONWear category I professional long-sleeved overalls and safety footwear (ref. Directive 89/686/CEE and standard EN 344). Wash body withsoap and water after removing overalls.
RESPIRATORY PROTECTIONIf the threshold value for one or more of the substances present in the preparation for daily exposure in the workplace or to a fractionestablished by the company’s prevention and protection service is exceeded, wear an FFP3 (ref. standard EN 141) type half mask.
The use of breathing protection equipment, such as masks with organic vapour and dust/mist cartridges, is necessary in the absence oftechnical measures limiting worker exposure. The protection provided by masks is in any case limited.
If the substance in question is odourless or its olfactory threshold is higher than the relative exposure limit and in the event of an emergency,or when exposure levels are unknown or the concentration of oxygen in the workplace is less than 17% volume, wear self-contained,open-circuit compressed air breathing apparatus (ref. standard EN 137) or fresh air hose breathing apparatus for use with full face mask, halfmask or mouthpiece (ref. standard EN 138).
9. Physical and chemical properties.
9.1. Information on basic physical and chemical properties.
There are no particular risks of reaction with other substances in normal conditions of use.
The product is stable in normal conditions of use and storage.
10.3. Possibility of hazardous reactions.
The vapours may also form explosive mixtures with the air.
Avoid overheating, electrostatic discharge and all sources of ignition.
10.6. Hazardous decomposition products.
In the event of thermal decomposition or fire, vapours potentially dangerous to health may be released.
11.1. Information on toxicological effects.
Acute effects: stinging eyes. Symptoms may include: rubescence, edema, pain and lachrymation. Contact with skin may cause: irritation,erythema, edema, dryness and chapped skin. Vapour inhalation may slightly irritate the upper respiratory tract. Ingestion may cause healthdisorders, including stomach pain and sting, nausea and sickness.
This product contains highly volatile substances, which may cause serious depression of the central nervous system (CNS) and havenegative effects, such as drowsiness, dizziness, slow reflexes, narcosis.
This product is dangerous for the environment and highly toxic for aquatic organisms. In the long term, it may even have negative effects onaquatic environment.
12.2. Persistence and degradability.
12.5. Results of PBT and vPvB assessment.
Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this productshould be evaluated according to applicable regulations.
Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations.
CONTAMINATED PACKAGING Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.
These goods must be transported by vehicles authorized to the carriage of dangerous goods according to the provisions set out in the currentedition of the Code of International Carriage of Dangerous Goods by Road (ADR) and in all the applicable national regulations.
These goods must be packed in their original packagings or in packagings made of materials resistant to their content and not reactingdangerously with it. People loading and unloading dangerous goods must be trained on all the risks deriving from these substances and on allactions that must be taken in case of emergency situations.
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture.
Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006.
Substances in Candidate List (Art. 59 REACH).
None.
Substances subject to authorisarion (Annex XIV REACH).
None.
Healthcare controls.
Workers exposed to this chemical agent must not undergo health checks, provided that available risk-assessment data prove that the risksrelated to the workers' health and safety are modest and that the 98/24/EC directive is respected.
No chemical safety assessment has been processed for the mixture and the substances it contains.
Text of hazard (H) indications mentioned in section 2-3 of the sheet: Specific target organ toxicity - single exposure, category 3 Aquatic Chronic 1Hazardous to the aquatic environment, chronic toxicity category 1Acute Tox. 4 Respiratory / skin sensitization, category 1 May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause thehazard>.
May cause genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure causethe hazard>.
May be fatal if swallowed and enters airways.
May cause an allergic skin reaction.
Very toxic to aquatic life with long lasting effects.
Text of risk (R) phrases mentioned in section 2-3 of the sheet: HARMFUL BY INHALATION AND IF SWALLOWED.
MAY CAUSE SENSITIZATION BY SKIN CONTACT.
VERY TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE AQUATICENVIRONMENT.
HARMFUL: MAY CAUSE LUNG DAMAGE IF SWALLOWED.
VAPOURS MAY CAUSE DROWSINESS AND DIZZINESS.
GENERAL BIBLIOGRAPHY1. Directive 1999/45/EC and following amendments2. Directive 67/548/EEC and following amendments and adjustments3. Regulation (EC) 1907/2006 (REACH) of the European Parliament4. Regulation (EC) 1272/2008 (CLP) of the European Parliament5. Regulation (EC) 790/2009 (I Atp. CLP) of the European Parliament6. Regulation (EC) 453/2010 of the European Parliament7. The Merck Index. - 10th Edition8. Handling Chemical Safety9. Niosh - Registry of Toxic Effects of Chemical Substances10. INRS - Fiche Toxicologique (toxicological sheet)11. Patty - Industrial Hygiene and Toxicology12. N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition Note for users:The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify thesuitability and thoroughness of provided information according to each specific use of the product .
This document must not be regarded as a guarantee on any specific product property.
The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current healthand safety laws and regulations. The producer is relieved from any liability arising from improper uses.

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