Microsoft word - permethrin d professional insecticide dust v2
MATERIAL SAFETY DATA SHEET 1. IDENTIFICATION OF MATERIAL AND SUPPLIER PRODUCT NAME: Barmac Permethrin D INSECTICIDAL GROUP: Group 3A APVMA REGISTRATION NUMBER: 49084 AUSTRALIAN DISTRIBUTOR: USE: Insecticide EMERGENCY PHONE NUMBERS:
Fire Brigade, Ambulance and Police Services: 000
FORM: Dust 2. HAZARD IDENTIFICATION
Classified as hazardous according to the criteria of SWA. Not dangerous according to the ADG Code.
RISK PHRASES: SAFETY PHRASES: HAZARD CATEGORY: Xi (Irritant) POISON SCHEDULE: Not applicable according to the SUSMP ADG Classification: Exempt. HAZCHEM CODE:UN NUMBER: Not Package Group: Not Applicable
3. COMPOSITION INFORMATION ON INGREDIENTS MIXTURE: CHEMICAL IDENTITY: PROPORTION: 4. FIRST AID MEASURES INHALED: If inhaled, remove to fresh air. If not breathing, give SWALLOWED: Rinse mouth. DO NOT induce vomiting. Keep
artificial respiration. If breathing is difficult, give oxygen. Seek
patient warm and at rest. Seek medical attention.
SKIN: Remove contaminated clothing and shoes immediately. EYES: In case of eye contact, check for and remove any contact
Wash off thoroughly with plenty of soap and water, if available
lenses.Immediately irrigate eyes with plenty of running water for at
with polyethylene glycol 400, subsequently rinse with water. I case
least 15 minutes, keeping eyelids open. Seek immediate medical
of skin irritation, applications of oils or lotions containing vitamin E
may be considered. If symptoms persist, call a physician
FIRST AID FACILITIES: Provide eye wash and shower facilities in workplace.
Trade Name: Permethrin D Professional Insecticide Dust
5. HEALTH EFFECTS INGESTION: Low oral toxicity. EYES: May irritate eyes. SKIN: May irritate skin. INHALED: Inhalation of dust may cause respiratory irritation. CHRONIC: The following symptoms may occur: Prolonged and repeated contact with skin, eyes or mucous membranes may cause irritation. Burning sensation, cough, sneezing, respiratory disorder, pulmonary oedema, nausea, vomiting, diarrhoea, abdominal pain, salivation, dizziness, blurred vision, headache, anorexia, somnolence, coma, seizures, convulsions, tremors, ataxia, and muscular fasciculation. 6. FIRE-FIGHTING MEASURES UNUSUAL FIRE & EXPLOSION HAZARDS: SPECIAL FIRE FIGHTING PROCEDURES:
In the event of fire decomposition products such as hydrogen
Must wear suitable breathing apparatus and protective suit when
chloride, carbon monoxide and carbon dioxide can be released.
FLAMMABILITY: Flammable HAZCHEM CODE: 2Z EXPOSURE LIMITS: EXTINGUISHING MEDIA:
ASCC has set the an exposure standard for talc as TWA 2.5 mg/m³
7. ACCIDENTAL RELEASE MEASURES PERSONAL PROTECTION: Use personal protective equipment. Avoid contact with spilled product or contaminated surfaces. Keep unauthorized people away. An emergency shower must be readily accessible to the work area. ENVIRONMENTAL PROTECTION: Do not allow into drains or waterways. If contamination of sewers or waterways has occurred advise local emergency services CLEAN UP AND DISPOSAL: Sweep up for disposal in designated land fill sites by the relevant authority that do not burn its refuse. Triple or pressure rinse bag before disposal. Dispose of rinsings in a disposal pit specifically marked and set up for this purpose, clear of waterways, desirable vegetation and roots. Break, crush, or puncture and bury containers in a local authority landfill. If not available bury the containers below 500mm in a disposal pit. Empty containers and product should not be burned. 8. HANDLING AND STORAGE HANDLING: Avoid contact with the eyes and skin. Avoid inhaling the dust. When using the product wear rubber gloves. Wash hands after use. STORAGE: Store in the closed original container in a dry, cool, well-ventilated area out of direct sunlight. TRANSPORT: According to AU01, Environmentally Hazardous Substances in packaging’s, IBC or any other receptacle not exceeding 500 kg or 500 L are NOT subject to the ADG Code. If greater than 500kg or L than the product is subject to regulation associated with ADG Class 9.
Trade Name: Permethrin D Professional Insecticide Dust
9. EXPOSURE CONTROL/PERSONAL PROTECTION EYE PROTECTION: Eye protection such as protective glasses PROTECTIVE MATERIAL TYPES: There is no specific
or goggles is recommended when this product is being used.
recommendation for any particular protective material type.
SKIN PROTECTION: Avoid contact with product and that you RESPIRATOR: A disposable dust mask must be to avoid dust
wear long sleeved shirt and long pants with rubber gloves
(preferably elbow-length) when skin contact is likely.
VENTILATION: EXPOSURE LIMITS (TWA):
This product should only be used where there is ventilation that is
ASCC has set the an exposure standard for talc as
adequate to keep exposure below the TWA levels. If necessary, use
10. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: BOILING POINT: SPECIFIC GRAVITY FLAMMABILITY: (20°C): FLASH POINT: VAPOUR DENSITY: VAPOR PRESSURE (20°C): SOLUBILITY: 11. STABILITY AND REACTIVITY STABILITY: INCOMPATIBILITY/ CONDTIONS TO AVOID:
Stable if stored in original container under normal ambient
Strong Acids, Strong Bases, Strong Oxidising Agents and halogen
HAZARDOUS DECOMPOSITION PRODUCTS: In the event of fire decomposition products such as hydrogen chloride, carbon monoxide and carbon dioxide can be released. 12. TOXICOLOGICAL INFORMATION ROUTE OF EXPOSURE: Inhalation, ingestion, eye and skin. TOXICITY (PERMETHRIN): Oral toxicity: LD rat: 1479 mg/kg (Permethrin 25:75 in corn oil)
Dermal toxicity: LD rabbit > 2000 mg/kg (Permethrin)
Inhalation toxicity: LC (3 hr) for mice and rats >685 mg/m air (Permethrin)
Skin irritation: Mild irritant rabbit (Permethrin) Eye irritation: Mild irritant rabbit (Permethrin)
CHRONIC: The following symptoms may occur: Prolonged and repeated contact with skin, eyes or mucous membranes may cause irritation. Burning sensation, cough, sneezing, respiratory disorder, pulmonary oedema, nausea, vomiting, diarrhoea, abdominal pain, salivation, dizziness, blurred vision, headache, anorexia, somnolence, coma, seizures, convulsions, tremors, ataxia, and muscular fasciculation CARCINOGENICITY No (ACGIH, IARC, NIOSH, ASCC)
Trade Name: Permethrin D Professional Insecticide Dust
13. ECOLOGICAL INFORMATION ECOTOXICITY: ( Permethrin):
Toxicity to fish: LC50 (Guppy (Poecilia reticulata)) 0.0076 mg/L Exposure time: 96 h Toxicity to aquatic invertebrates: EC50 (Water flea (Daphnia magna)) 0.00017 mg/L Exposure time: 48 h Toxicity to aquatic plants: EC50 (Selenastrum capricornutum) 0.497 mg/L Exposure time: 96 h
14. DISPOSAL WASTE DISPOSAL METHOD: Triple or pressure rinse bag before disposal. Dispose of rinsings in a disposal pit specifically marked and set up for this purpose, clear of waterways, desirable vegetation and roots. Break, crush, or puncture and bury containers in a local authority landfill. If not available bury the containers below 500mm in a disposal pit. Empty containers and product should not be burned. 15. TRANSPORT INFORMATION UN NO: Not Applicable SPECIAL PROVISIONS: Not applicable SHIPPING NAME: Not applicable 16. REGULATORY INFORMATION POISONS SCHEDULE: Exempt HAZARD CATEGORY: Not classified PACKAGING AND LABELLING: Not set CLASSIFICATION: 2.1 Flammable gas. 16. OTHER INFORMATIONS This MSDS contains only safety-related information. For other data see product literature. Acronyms: ADG Code: Australian Code for the Transport of Dangerous Goods by Road and Rail, 7th Edition SWA Safe Work Australia, formerly ASCC and NOHSC CAS Number Chemical Abstracts Service Registry Number SUSMP Standard for the Uniform Scheduling of Medicines & Poisons UN: United Nations Number TWA: Time weight average.
The information provided in this Safety Data Sheet has been obtained from sources believed to be reliable. Barmac Pty Ltd. provides no warranties; either expressed or
implied, and assumes no responsibility for the accuracy or completeness of the data contained herein. This information is offered for your consideration and investigation.
The user is responsible to ensure that they have all current data relevant to their particular use.
Trade Name: Permethrin D Professional Insecticide Dust
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