923021_gb_aenglish.ps

SAFETY DATA SHEET
According to EC-directive 93/112/EC
Pending
PERMETHRIN 25/75
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Product label name

Supplier
SUMITOMO CHEMICAL (UK) PLCHoratio House77-85 Fulham Palace RdLondon W6 8JAUnited KingdomTel.: +44 208 600 7700 Emergency telephone
+ 31 570679211 (Fax. + 31 570679801)Akzo Nobel Chemicals-Deventer-NL + 44-1634280888Akzo Nobel Chemicals-Gillingham-GB 2. COMPOSITION/INFORMATION ON INGREDIENTS
This product is to be considered as a substance in conformance to EC directives
Information on hazardous ingredients
Chemical description
Composition / information on ingredients
Number

CAS-number
Chemical name
EC-number
Annex-1 number
Symbol(s)
Risk-phrase(s)
3. HAZARDS IDENTIFICATION
Harmful if swallowed.
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
4. FIRST AID MEASURES
Symptoms and effects

Possible symptoms: diarrhoea, salivation, tremor,hyperexcitability and hypersensitivity.
Synthetic pyrethroids can produce paresthesias.
First aid
In all cases of doubt, or when symptoms persist, seek medical attention.
Inhalation
In case of accident by inhalation: remove casualty to fresh air and keep at rest. Obtainmedical attention immediately (show this Safety Data Sheet).
Remove contaminated clothing. Wash immediately with soap and water. Obtain medicalattention immediately (show this Safety Data Sheet).
Rinse thoroughly with plenty of water. Eyelids should be held away from the eyeball toensure thorough rinsing. Seek medical advice if irritation develops.
Ingestion
Rinse mouth, give water to drink. Never induce vomiting in unconscious or confusedpersons. Seek medical advice.
Advice to physician
Symptomatic treatment is advised.
Consult National Poison Center.
5. FIRE-FIGHTING MEASURES
Extinguishing media

dry chemical powder, Carbon dioxide.
Large fires: waterspray or foam Unsuitable extinguishing media waterjet.
Special exposure hazards
Hazardous decomposition/
May emit toxic and irritating fumes under fire conditions.
combustion products
Protective equipment

Wear self contained breathing apparatus. Wear suitable protective clothing. See alsoSection 8.
Other information
Cool closed containers with water.
Water used to extinguish a fire should not be allowed to enter the drainage system orwater courses.
Product code
Date of last issue
aEnglish
SAFETY DATA SHEET
According to EC-directive 93/112/EC
Pending
PERMETHRIN 25/75
6. ACCIDENTAL RELEASE MEASURES
Personal precautions

For personal protection see Section 8.
Environmental precautions
Do not allow to escape into sewage system or water courses.
Methods for cleaning up
In case of spill (liquid), soak it up immediately with suitable absorbent, such as sawdustor granular absorbent clay. Sweep up and put it into a container for disposal ( SeeSection 13). Rinse remnant with plenty of water. Do not allow to enter drains or watercourses.
7. HANDLING AND STORAGE
Handling

Keep away from food, drink and animal feedingstuffs. Avoid contact with skin and eyes.
For personal protection see Section 8.
Fire and explosion prevention
Storage requirements
Store in a dry well ventilated place away from sources of heat and direct sunlight.
Store at ambient temperatures. Protect from frost.
Keep only in the original container.
Other information
To maintain quality: Store in polyethylene.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering controls

Exposure limits
No exposure limits have been established for this material.
Personal protection
Respiratory
Skin and body
Other information
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance

Boiling point/range
Melting point/range
Flash point
Flammability
Autoignition temperature
Explosive properties
Explosion limits
Oxidizing properties
Vapour pressure
Bulk density
Solubility in water
Solubility in other solvents
Partition coefficient
n-octanol/water
Relative vapour density (air=1)

Viscosity
10. STABILITY AND REACTIVITY
Stability

Stable under recommended storage and handling conditions (see section 7).
Conditions to avoid
Materials to avoid
Hazardous decomposition
Emits toxic fumes under fire conditions (See also Section 5).
products
Product code
Date of last issue
aEnglish
SAFETY DATA SHEET
According to EC-directive 93/112/EC
Pending
PERMETHRIN 25/75
11. TOXICOLOGICAL INFORMATION
Name

Acute toxicity
Oral LD50
Dermal LD50
Inhalation LC50
Irritation
Sensitization
Genotoxicity
Not mutagenic. Not teratogenic. not carcinogenic 12. ECOLOGICAL INFORMATION
Name

Ecotoxicity
fish

13. DISPOSAL CONSIDERATIONS
Product

According to local regulations. For further advice contact manufacturer.
Contaminated packaging
14. TRANSPORT INFORMATION
Land transport (ADR/ RID)
ADR class
ADR item number
RID class
RID item number
Hazard Identification No.
Substance Identification No. 3352
TREM-Card
UN number
Proper Shipping Name
Pyrethroid pesticide, liquid, toxic (Permethrin) IMO/IMDG code
Packing group
UN number
Marine pollutant
Proper Shipping Name
Pyrethroid pesticide, liquid, toxic (Permethrin) ICAO-TI/IATA-DGR
UN number
Packing group
Proper Shipping Name
Pyrethroid pesticide, liquid, toxic (Permethrin) 15. REGULATORY INFORMATION
Chemical description

Labelling according to EC directives
EC-number
Classification based on
Symbol(s)
Product code
Date of last issue
aEnglish
SAFETY DATA SHEET
According to EC-directive 93/112/EC
Pending
PERMETHRIN 25/75
R(isk) phrase(s)

R22: Harmful if swallowedR50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in theaquatic environment S(afety) phrase(s)
S20/21: When using do not eat, drink or smokeS46: If swallowed, seek medical advice immediately and show this container or labelS60: This material and its container must be disposed of as hazardous wasteS61: Avoid release to the environment. Refer to special instructions/Safety data sheets 16. OTHER INFORMATION
This information only concerns the above mentioned product and does not need to be valid if used with other product(s) or
in any process. The information is to our best present knowledge correct and complete and is given in good faith but without
warranty. It remains the user's own responsibility to make sure that the information is appropriate and complete for his
special use of this product.
History
Date of printing/
pdf file generated
Revision

Composed by
Product code
Date of last issue
aEnglish

Source: http://wefco-africa.co.za/assets/msds/Permethrin_MSDS.pdf

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