MATERIAL SAFETY DATA SHEET Emergency Telephone (262) 251-4977 Section 1 – Company Name and Product Information Company Name: Alliance Group, Inc. Address: N114 W18621 Clinton Drive
Product name: Oxytrol Product code: 0111 Chemical Family: Sulfite Solution Revised MSDS: Section 2 – Hazards Identification EMERGENCY OVERVIEW: DANGER! CORROSIVE. Harmful or fatal if swallowed. Harmful if inhaled. May cause an allergic reaction to skin, respiratory tract or if swallowed. Physical State: POTENTIAL HEALTH EFFECTS Routes Of Exposure: Eyes. Ingestion. Inhalation. Skin. Target Organs: None known. Eye Contact: Solutions will cause irritation or burns to the eyes. Skin Contact: Contact may cause: allergic skin reaction. Solutions will cause skin irritation. Skin Absorption: No data available. Inhalation: Dusts or mists may irritate: respiratory tract. May cause severe or deadly allergic reaction in some asthmatics or sulfite sensitive individuals. Possible signs and symptoms of allergic reaction may include hives, respiratory distress, flushing, gastrointestinal disturbances and contact dermatitis. Severe cases result in respiratory arrest, unconsciousness or coma. Ingestion: May cause: gastrointestinal irritation. nausea. vomiting. death. Large amounts may cause: violent colic. diarrhea. circulatory disturbances. central nervous system depression. May cause severe or deadly allergic reaction in some asthmatics or sulfite sensitive individuals. Medical Conditions Aggravated By Exposure To Product: Respiratory system disorders. May cause severe and possibly fatal allergic reactions if inhaled or swallowed by some asthmatics and sulfite- sensitive individuals. Other: This product is not for drug use. Only Food Grade material is for use as a food additive. Cancer Information: This product does not contain greater than 0.1% of the known or potential carcinogens listed in NTP, IARC, or OSHA. Potential Environmental Effects: See Section 12. Section 3 – Composition / Hazardous Ingredients CAS Number Chemical Component % by Weight OSHA Hazard Section 4 – First Aid Measures Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes while holding eyelids open. Tilt head to avoid contaminating unaffected eye. Get immediate medical attention. Skin Contact: Immediately flush skin with plenty of water while removing contaminated clothing and shoes. Do not reuse clothing or shoes until cleaned. If irritation develops or persists, get medical attention. Wash with soap and water. Inhalation: Remove to fresh air. If breathing is difficult, administer oxygen. If not breathing, give artificial respiration, preferably mouth-to-mouth. GET MEDICAL ATTENTION IMMEDIATELY. Ingestion: If swallowed, wash out mouth with water provided person is conscious. Call a physician immediately. Give 1-2 glasses of water to drink. Note to Physicians: Treat symptomatically. Note potential for anaphylactic shock with allergic individuals. Risk of sulfur dioxide formation by reaction with gastric acid after swallowing. Section 5 - Fire Fighting Measures Flash Point: None.
Lower Explosion Limit: N.A. Upper Explosion Limit: N.A. Extinguishing Media: Not flammable. Use extinguishing agents appropriate for surrounding fire. Fire Fighting Methods: Evacuate area of unprotected personnel. Wear protective clothing including NIOSHApproved self-contained breathing apparatus. Remain upwind of fire to avoid hazardous vapors and decomposition products. Use water spray to cool fire exposed containers and disperse vapors. Fire And Explosion Hazards: None known. Hazardous Combustion Products: At elevated temperatures, product will decompose generating: Sulfur dioxide Section 6 – Accidental Release Measures Spill Clean-Up Procedures: CORROSIVE MATERIAL. Evacuate unprotected personnel from area. Maintain adequate ventilation. Follow personal protective equipment recommendations found in Section 8. Never exceed any occupational exposure limit. Contain spill, place into drums for proper disposal. Flush remaining area with water to remove trace residue and dispose of properly. Provide ventilation to clear sulfur dioxide fumes which may be generated by the sodium sulfite component. Avoid direct discharge to sewers and surface waters. Notify authorities if entry occurs. Section 7 - Handling and Storage Handling: Avoid contact with eyes, skin, and clothing. Use with adequate ventilation. Do not swallow. Avoid breathing vapors, mists, or dust. Do not eat, drink, or smoke in work area. Wash thoroughly after handling. Storage: CORROSIVE MATERIAL. Store in a cool, well ventilated area, out of direct sunlight. Store in a dry location away from heat. Keep away from incompatible materials. Keep containers tightly closed. Do not store in unlabeled or mislabeled containers. Keep containers tightly closed. Do not store in unlabeled or mislabeled containers Section 8 – Exposure Control / Personal Protection Exposure Guidelines: Component ACGIH TWA ACGIH STEL/C Engineering Controls: General room ventilation and local exhaust are required. Avoid creating dust or mist. Maintain adequate ventilation. Do not use in closed or confined spaces. Keep levels below exposure limits. To determine exposure levels, monitoring should be performed regularly. Eye/Face Protection: Wear chemical safety goggles while handling this product. Do not wear contact lenses. Skin Protection: Prevent contact with this product. Wear gloves and protective clothing depending on condition of use. Protective gloves: Impervious. Respiratory Protection: Respiratory protection may be required to avoid overexposure when handling this product. If exposure limits are exceeded, wear: NIOSH-Approved respirator for dusts, mists, and/or SO2 vapors as conditions indicate. NIOSH-Approved Supplied Air Respirator (SAR). NIOSH-Approved self-contained breathing apparatus. DO NOT exceed limits established by the respirator manufacturer. All respiratory protection programs must comply with OSHA 29 CFR 191 0.134 and ANSI Z88.2 requirements and must be followed whenever workplace conditions require a respirator's use. Other Protective Equipment: Eye-wash station. Safety shower. Rubber apron. Rubber boots. Protective clothing. General Hygiene Conditions: Wash with soap and water before meal times and at the end of each work shift. Section 9 – Physical and Chemical Properties. Physical State: Color: Clear. Water white Specific Gravity: Solubility in water: Freezing Point: % Volatiles: N.D. Vapor Pressure: Vapor Density: N.D. Section 10 – Stability and Reactivity Stability: Stable under normal conditions. Conditions To Avoid: Avoid elevated temperatures. Incompatible Materials: Acids. Oxidizing agents. Nitrites. Nitrates. Hazardous Decomposition Products: Sulfur dioxide. Sulfur oxides. Sodium sulfide residue. Possibility of Hazardous Reactions: Hazardous polymerization will not occur under normal conditions. Contact with acids will release sulfur dioxide. Contact with strong oxidizers causes vigorous exothermic reactions Section 11 – Toxicological Information LD50 Oral: LD50 Skin: LC50 Inhalation: Section 12 – Ecological Information Ecotoxicological Information: Chemical Fate Information: Section 13 –Disposal Considerations Hazardous Waste Number: N.A. Waste disposal methods: Dispose of in accordance with all local, state, and federal regulations. Regulations may vary in different locations. Since emptied containers retain product residue, follow label warnings even after container is emptied. Section 14 – Transportation Information Proper Shipping Name: Corrosive liquid, basic, inorganic, n.o.s. (contains sodium sulfite) Hazard Class: 8 UN Number: UN3266 Packing Group: II Label required: Corrosive Section 15 – Regulatory Information TSCA Inventory Status: This product or all components of this product are listed on the Inventory of Chemical Substances. SARA Title III Section 311/312 Category: Immediate (Acute) Health Hazard: SARA Section 302/304/313/HAP: Component CERCLA RQ SARA RQ SARA TPQ SARA 313 California - The following components are listed under Proposition 65: Lead <= 3 ppm Wisconsin :The following components are listed as a Wisconsin HAP: None Section 16 –Additional Information HMIS/NFPA Label Information Complies with CFR Title 21 Section 173.310 for boiler water and steam which may contact dairy products. MSDS DATED: December 1, 2008 MSDS Prepared by: PMay Reason for Revision: Change in format. The data in this Material Safety Data Sheet relates to the specific material designated and does not relate to its use in combination with any other material or process. The data contained is believed to be correct. However, since conditions of use are outside our control it should not be taken as warranty or representation for which Alliance Group, Inc. assumes legal responsibility. This information is provided solely for your consideration, investigation, and verification.
2014 Fort Creek Baptist Church Youth Waiver for Medical Treatment and Participation in Activities (Youth) Name: _______________________________________________ Name Called _______________________________ Address ________________________________________________________________________________________________ City: _____________________________________ State: __________________ Zip
Committee for Human Medicinal Products (CHMP) CHMP Pharmacokinetics Working Party (PKWP) Questions & Answers: Positions on specific questions addressed to the Pharmacokinetics Working Party Background In the context of assessment procedures, the Pharmacokinetics Working Party (PKWP), or its predecessor the Therapeutic Subgroup on Pharmacokinetics of the Efficacy Working Party (EWP-PK sub